When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | Cl2O6_GoodeveRichardson(1937)_273-276.5K_193.6-353.9nm.txt |
NAME: | dichlorine hexoxide, chloryl chlorate |
FORMULA: | Cl2O6 |
AUTHOR(YEAR): | GoodeveRichardson(1937) |
T: | 273-276.5K |
λ: | 193.6-353.9nm |
BIBLIOGRAPHY: |
C.F. Goodeve and F.D. Richardson, "The absorption spectrum of chlorine trioxide and chlorine hexoxide",
Trans. Faraday Soc. 33, 453-457 (1937);
DOI: 10.1039/TF9373300453
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COMMENTS: | Structure: O3ClOClO2
Absorption measurements by the photographic method (T = 273 and 276.5 K) Molar extinction coefficients vs. wavenumber plotted as a smooth fit of about 50 measured data points at 220-345 nm in Fig. 1 have been digitized and converted to absorption cross sections (conversion factor 3.8235×10-21) vs. wavelength
The spectrum has originally been attributed to ClO3 Because of its shape and in spite of the low absorption cross sections, the spectrum has been attributed to Cl2O6 by M.I. Lopez and J.E. Sicre, "Physicochemical properties of chlorine oxides. 1. Composition, ultraviolet spectrum, and kinetics of the thermolysis of gaseous dichlorine hexoxide, J. Phys. Chem. 94, 3860-3863 (1990); DOI: 10.1021/j100372a094 |
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